The veteran duo was voted into the Country Music Hall of Fame in 2019.
The ceremony will be held on April 3 in Atlanta.
Ángela Aguilar, Megan Moroney & Muni Long will also perform, while Tanner Adell, Julia Michaels, Mickey Guyton, Kali Uchis, Madison Beer, Summer Walker & Zara Larsson are set to present.
The annual event returns to Lagos, Nigeria, after two years in Atlanta.
Her close collaborator A.G. Cook has been awarded the producer of the year title.
The musician's pal and collaborator Taylor Swift received the honor in 2010.
The London-born musician was an executive producer of Charli XCX's Brat LP.
The cast of Only Murders in the Building won best ensemble at the 2025 awards.
The special is set to air live coast-to-coast on CBS and Paramount+.
Winners will be announced on April 30.
