Sabrina Carpenter, Shaboozey and Teddy Swims will also perform at the March 1 ceremony.
The ceremony will take place at London's O2 Arena in March.
Kendrick Lamar, Ariana Grande and The Beatles are among artists who either did better or worse than expected.
Dua Lipa, The Last Dinner Party and jazz group Ezra Collective follow with four nominations each.
In her first interview following her historic BRITs sweep, RAYE recounts her journey as an independent artist and what she has planned next.
You want to start off your show with a bang? Call Dua Lipa.
RAYE is set to perform on the March 2 show, along with Calvin Harris & Ellie Goulding, Dua Lipa, Kylie Minogue, Rema, Tate McRae and more.
Taylor Swift received the honor three years ago.
Here's every artist who has earned at least five BRIT Awards nominations in a single year.
Baby Queen, You And Me At Six, Aitch, Pendulum