The show will take over the Moody Center in Austin, Texas, on April 7.
The artist will also deliver the debut live performance of "Put It In a Song," the first music from her upcoming album.
Keith Urban & Sam Hunt are also slated in the first round of performers, Billboard can exclusively reveal.
Both artists are still in the running for video of the year, as is Cody Johnson.
The fan-voted country music awards show will air Sunday, April 7 on CBS.
The event will be held at the Moody Center again.
You know that Kane and Jelly Roll won big on Sunday, but do you know what records they set?
The rising star revealed No Doubt was the second concert he ever attended.
The long-rumored couple made their red carpet debut at the awards show Sunday night (April 2).
Johnson, Judd, LeAnn Rimes, Slash, Billy Gibbons, Paul Rodgers, Chuck Leavell and Warren Haynes all came together to honor the late Gary Rossington with a rousing performance.
