The Black Keys, Reneé Rapp, Remi Wolf, Nathaniel Rateliff & The Night Sweats and Leon Bridges will also perform at the three-day event.
La Flame greeted the TV personality as he arrived to see Caitlin Clark's record-breaking performance at Sunday's NCAA game.
Hokies supporters began belting the chorus to the heavy metal 1991 classic a capella during Friday night's game against Chattanooga.